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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

One-pot Synthesis of a New Hydroxamic Acid and its Complexes with Metals

Author(s): Gulu Abbasova and Ajdar Medjidov*

Volume 19, Issue 10, 2022

Published on: 11 January, 2022

Page: [837 - 841] Pages: 5

DOI: 10.2174/1570178619666220111121743

Price: $65

Abstract

A one-pot conversion of 2-hydroxy-1-naphthoic aldehyde to hydroxamic acid was described. An efficient photoorganocatalytic method of synthesis was developed. The obtained hydroxamic acid was identified by various physicochemical methods such as IR, UV- and NMR-spectroscopy. Solid colored complexes of copper (II) and iron (II), respectively, green and brown colours with the obtained hydroxamic acid were synthesized in ethanol medium for the first time. The molar ratio of ligand and metal in the complex was 2:1. Their structures were established using IR, UV- spectroscopy and thermogravimetric analysis.

Keywords: Hydroxamic acids, one-pot synthesis, photoorganocatalysis, complexing, NMR-spectroscopy, metals.

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