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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Synthesis and Catalytic Application of Ru-Deposited Magnetic Nanoparticles for the Selective Hydrogenation of CO2 Gas

Author(s): Prashant Gautam and Vivek Srivastava*

Volume 19, Issue 9, 2022

Published on: 10 February, 2022

Page: [705 - 710] Pages: 6

DOI: 10.2174/1570178618666211119115822

Price: $65

Abstract

In this report, a hybrid terpyridine (tpy) ligand functionalize with magnetic support was synthesized to obtain well-dispersed Ru NPs with a 2.0±0.5 nm mean size. This material was further analyzed using different analytical techniques before utilizing it as a catalyst for the CO2 hydrogenation reaction. A noticeable application of Ru-deposited magnetic nanoparticles as catalysts was observed during the CO2 hydrogenation. We successfully synthesized the formic acid with a high TON value under high-pressure reaction conditions. Easy recovery of the catalyst under the applied magnetic field helped us to reuse the catalyst up to 6 times with good TON and TOV value.

Keywords: Magnetic support, silica shell, Ru NPs, formic acid, pyridine-based ligand, formic acid.

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