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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Microwave-assisted, Copper-free Sonogashira Coupling Between Aryl Halides and Terminal Alkynes Using Recyclable Ionic Liquid and Catalyst

Author(s): Dau Xuan Duc* and Nguyen Van Quoc

Volume 19, Issue 1, 2022

Published on: 20 August, 2021

Page: [28 - 33] Pages: 6

DOI: 10.2174/1570178618666210820101129

Price: $65

Abstract

An efficient method for the Sonogashira coupling reaction between aryl halides and terminal alkynes has been developed. The reaction was performed in ionic liquid 1-butyl-3- methylimidazolium tetrafluoroborate ([Bmim][BF4]) under microwave irradiation. High yields of products were obtained in a very short reaction time. Moreover, the medium and catalyst could be recovered and reused three times without considerable decrease in reaction yields.

Keywords: Coupling reaction, terminal alkynes, ionic liquid, microwave, trimethylsillylacetylene, iodide.

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