Abstract
Mechanisms of transglycosylation reactions in the nucleoside chemistry and their modern interpretations are presented. Special attention is paid to the formation of kinetically controlled and thermodynamic products, reaction intermediates, correlation of tautomerism and regioselectivity in glycosyl migration reactions, their stereoselectivity and reversibility as well as side-reactions like anomerization or cyclization. Some synthetic applications of transglycosylation are also discussed.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Books
Advances in Organic Synthesis
The Synthetic Methods, Structures, and Properties of the Ca-C σ Bond Organocalcium Containing Compounds
Advances in Organic Synthesis
Chemistry of Bipyrazoles: Synthesis and Applications
Advances in Organic Synthesis
Advanced Nanocatalysis for Organic Synthesis and Electroanalysis
Advances in Organic Synthesis
Advances in Organic Synthesis
9