Palladium Promoted Copolymerization of Carbon Monoxide with Polar or Non-polar Olefinic Monomers

Yanlin       Zong; Qiankun       Li; Hongliang       Mu; Zhongbao       Jian

doi:10.2174/1385272824999201102221113

Abstract

The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a family of widely used materials. In the catalytic preparation of these materials, palladium(II) catalysts represent the most successful catalytic systems. The production of both alternating and non-alternating polyketones has been achieved, with a great difference in their physical properties. Herein, a variety of palladium(II) catalysts, employed for the copolymerization of CO with various olefinic monomers, such as ethylene, α -olefins, styrene and polar vinyl monomers, are fully summarized. The influence of important factors, such as solvents and counterions on specific copolymerization, is also discussed. This review aims to enlighten the design of new Pd catalysts with improved properties, as well as the development of new polyketone materials.

Keywords: Homogeneous catalysis, coordination polymerization, polyketone, polyolefin, carbon monoxide, olefin, palladium, copolymerization.

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DOI https://dx.doi.org/10.2174/1385272824999201102221113	Print ISSN 1385-2728
Publisher Name Bentham Science Publisher	Online ISSN 1875-5348

Current Organic Chemistry

Palladium Promoted Copolymerization of Carbon Monoxide with Polar or Non-polar Olefinic Monomers

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Catalytic C-H bond activation as a tool for functionalization of heterocycles

Current Organic Chemistry

Palladium Promoted Copolymerization of Carbon Monoxide with Polar or Non-polar Olefinic Monomers

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Catalytic C-H bond activation as a tool for functionalization of heterocycles

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