Abstract
Catalytic C-H activation is a powerful method for organic synthesis. In recent years, scientists have made great progress by developing transitional metals for catalyzing CH functionalization reaction. In this review, we summarized and highlighted recent progress in C-H activation with copper, cobalt, iron, manganese, and nickel as catalysts.
Keywords: C-H activation, multicomponent reactions, synthesis, catalyst, copper, cobalt, nickel, iron, manganese.
Graphical Abstract
[http://dx.doi.org/10.1021/cr900122p] [PMID: 19821608]
[http://dx.doi.org/10.1021/cr900184e] [PMID: 20078038]
[http://dx.doi.org/10.1021/cr900005n] [PMID: 19438203]
[http://dx.doi.org/10.1021/cr500610p] [PMID: 25749375]
[http://dx.doi.org/10.1016/j.molcata.2016.06.020]
[http://dx.doi.org/10.1021/cr00100a004]
[http://dx.doi.org/10.1021/jo900513z] [PMID: 19382756]
[http://dx.doi.org/10.1021/acs.joc.6b01393] [PMID: 27504671]
[http://dx.doi.org/10.1002/adsc.200900426]
[http://dx.doi.org/10.1002/anie.200705420] [PMID: 18228236]
[http://dx.doi.org/10.1039/C9CC06609H] [PMID: 31621700]
[http://dx.doi.org/10.1021/jo400159y] [PMID: 23565982]
[http://dx.doi.org/10.1038/nchem.1669] [PMID: 23787750]
[http://dx.doi.org/10.1021/cr050980b] [PMID: 17439184]
[http://dx.doi.org/10.1002/anie.201301451] [PMID: 24105797]
[http://dx.doi.org/10.1021/ja01628a120]
[http://dx.doi.org/10.1021/ar800039x] [PMID: 18588321]
[http://dx.doi.org/10.1002/anie.200800012] [PMID: 18412184]
[http://dx.doi.org/10.1021/acs.orglett.5b00337] [PMID: 25714854]
[http://dx.doi.org/10.1021/ja511011m] [PMID: 25472496]
[http://dx.doi.org/10.1021/acscatal.9b03194]
[http://dx.doi.org/10.1021/acs.orglett.9b00187] [PMID: 30735399]
[http://dx.doi.org/10.1021/acscatal.9b03620]
[http://dx.doi.org/10.1002/ange.201404579]
[http://dx.doi.org/10.1021/ja5008432] [PMID: 24650237]
[http://dx.doi.org/10.1002/adsc.201301110]
[http://dx.doi.org/10.1002/anie.201404019] [PMID: 24889319]
[http://dx.doi.org/10.1021/jo501361k] [PMID: 25102352]
[http://dx.doi.org/10.1021/ol005928a] [PMID: 10880218]
[http://dx.doi.org/10.1021/acscatal.5b00322]
[http://dx.doi.org/10.1021/acscatal.5b00581]
[http://dx.doi.org/10.1021/ol503744a] [PMID: 25671773]
[http://dx.doi.org/10.1021/jm0408924] [PMID: 15801862]
[http://dx.doi.org/10.1021/jm050335x] [PMID: 16134952]
[http://dx.doi.org/10.1021/ol503680d] [PMID: 25602639]
[http://dx.doi.org/10.1021/ja512728f] [PMID: 25625542]
[http://dx.doi.org/10.1021/acs.orglett.5b00910] [PMID: 25945401]
[http://dx.doi.org/10.1021/cs501860b]
[http://dx.doi.org/10.1021/acs.orglett.6b01632] [PMID: 27435354]
[http://dx.doi.org/10.1021/acscatal.7b00207]
[http://dx.doi.org/10.1021/acs.orglett.9b02145] [PMID: 31343889]
[http://dx.doi.org/10.1021/acs.joc.9b00595] [PMID: 31083904]
[http://dx.doi.org/10.1021/jacs.5b04548] [PMID: 26057139]
[http://dx.doi.org/10.1021/jacs.5b08039] [PMID: 26334367]
[http://dx.doi.org/10.1021/ol503607h] [PMID: 25668487]
[http://dx.doi.org/10.1021/jacs.0c02355] [PMID: 32195579]
[http://dx.doi.org/10.1039/C5CY01299F]
[http://dx.doi.org/10.1021/acscatal.6b00993]
[http://dx.doi.org/10.1021/om2005673]
[http://dx.doi.org/10.1021/acs.orglett.5b00990] [PMID: 25942045]
[http://dx.doi.org/10.1021/acs.orglett.5b01128] [PMID: 25928271]
[http://dx.doi.org/10.1021/acs.orglett.5b02217] [PMID: 26366464]
[http://dx.doi.org/10.1021/ol403021p] [PMID: 24224695]
[http://dx.doi.org/10.1021/ol502314p] [PMID: 25202856]
[http://dx.doi.org/10.1021/jacs.5b01671] [PMID: 25815529]
[http://dx.doi.org/10.1002/anie.201309584] [PMID: 24482119]
[http://dx.doi.org/10.1021/acscatal.6b01120]
[http://dx.doi.org/10.1021/acs.orglett.8b02736] [PMID: 30272983]
[http://dx.doi.org/10.1002/anie.201210029] [PMID: 23417843]
[http://dx.doi.org/10.1021/ol501534z] [PMID: 24983740]
[http://dx.doi.org/10.1021/acs.orglett.5b00775] [PMID: 25860622]
[http://dx.doi.org/10.1002/anie.201406594] [PMID: 25088928]
[http://dx.doi.org/10.1021/jacs.5b12150] [PMID: 26907535]
[http://dx.doi.org/10.1002/anie.201509603] [PMID: 26663680]
[http://dx.doi.org/10.1021/ja303250t] [PMID: 22694754]
[http://dx.doi.org/10.1021/jacs.5b01784] [PMID: 25831473]
[http://dx.doi.org/10.1021/jacs.5b04818] [PMID: 26061014]
[http://dx.doi.org/10.1021/ja4106368] [PMID: 24215539]
[http://dx.doi.org/10.1002/chem.201501134] [PMID: 25950870]
[http://dx.doi.org/10.1021/ja5066015] [PMID: 25032786]
[http://dx.doi.org/10.1002/(SICI)1521-3773(19990614)38:12<1698:AID-ANIE1698>3.0.CO;2-6] [PMID: 29711186]
[http://dx.doi.org/10.1021/ol5004115] [PMID: 24635116]
[http://dx.doi.org/10.1002/anie.201311024] [PMID: 24596034]
[http://dx.doi.org/10.1021/acs.joc.9b00625] [PMID: 31117558]
[http://dx.doi.org/10.1021/cr300527g] [PMID: 23786461]
[http://dx.doi.org/10.1002/anie.201404822] [PMID: 25100616]
[http://dx.doi.org/10.1039/C3CC48767A] [PMID: 24448428]
[http://dx.doi.org/10.1021/acs.orglett.5b01192] [PMID: 25992950]
[http://dx.doi.org/10.1021/acs.joc.5b01351] [PMID: 26259687]
[http://dx.doi.org/10.1021/acs.organomet.9b00443]
[http://dx.doi.org/10.1021/ja061715q] [PMID: 16719450]
[http://dx.doi.org/10.1021/jacs.5b05529] [PMID: 26247373]
[http://dx.doi.org/10.1021/jacs.5b02435] [PMID: 25924012]
[http://dx.doi.org/10.1002/anie.200902262] [PMID: 19591182]
[http://dx.doi.org/10.1021/acscatal.5b00310]
[http://dx.doi.org/10.1021/acs.joc.5b01302] [PMID: 26247345]
[http://dx.doi.org/10.1021/acs.orglett.5b01940] [PMID: 26226391]
[http://dx.doi.org/10.1021/acs.orglett.5b00193] [PMID: 25695876]
[http://dx.doi.org/10.1021/jacs.6b01337] [PMID: 27064340]
[http://dx.doi.org/10.1021/ja905056z] [PMID: 19799379]
[http://dx.doi.org/10.1002/chem.201001960] [PMID: 20981670]
[http://dx.doi.org/10.1016/j.tetlet.2017.05.074]
[http://dx.doi.org/10.1021/acs.orglett.9b02120] [PMID: 31310137]
[http://dx.doi.org/10.1055/s-0033-1339299]
[http://dx.doi.org/10.1021/cr900269x] [PMID: 20143877]
[http://dx.doi.org/10.1002/anie.200702256] [PMID: 17654472]
[http://dx.doi.org/10.1039/b814694b] [PMID: 19048155]
[http://dx.doi.org/10.1021/jo902072q] [PMID: 20000351]
[http://dx.doi.org/10.1039/C29710001595]
[http://dx.doi.org/10.1021/jacs.8b09095] [PMID: 30698423]
[http://dx.doi.org/10.1021/ja311689k] [PMID: 23286776]
[http://dx.doi.org/10.1021/acs.orglett.5b03474] [PMID: 26741796]
[http://dx.doi.org/10.1002/ejoc.201501405]
[http://dx.doi.org/10.1021/acs.orglett.9b02554] [PMID: 31437000]
[http://dx.doi.org/10.1021/acs.orglett.8b03924] [PMID: 30604972]