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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Review Article

Highly Selective Hydroiodination of Carbon-Carbon Double or Triple Bonds

Author(s): Yuki Yamamoto, Shin-ichi Kawaguchi, Shintaro Kodama, Akihiro Nomoto and Akiya Ogawa*

Volume 24, Issue 18, 2020

Page: [2153 - 2168] Pages: 16

DOI: 10.2174/1385272824666191227111257

Price: $65

Abstract

Iodine is an element that exhibits characteristic features of heavy halogen, and several compounds containing iodine constitute important synthetic intermediates due to synthetically easy manipulation. To utilize iodine units for organic synthesis, a highly regio- and stereoselective introduction of iodine to versatile building blocks is significant, and a lot of research works for the selective introduction of iodine to alkynes or alkenes have been conducted. In this review article, we describe regio- and stereoselective hydroiodination to multiple bonds of building blocks, and its synthetic applications as key intermediates to construct several important compounds in organic chemistry.

Keywords: Hydroiodination, regio- and stereoselective synthesis, alkene and alkyne activations, green synthesis, cross-coupling, iodine reagents.

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