Abstract
The application of stabilized metal carbenes as reactive intermediates in synthesis has greatly expanded because of the wide array of structures that are available from these reactions. In order to expand the usefulness of these reactions, several investigators have focused on the development of chiral catalysts that cab effect asymmetric carbene reactions. This review will cover the development and application of these catalysts.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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