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Nanoscience & Nanotechnology-Asia

Editor-in-Chief

ISSN (Print): 2210-6812
ISSN (Online): 2210-6820

Research Article

Preparation and Characterization of Rutile Titania Nanofluids Stabilized in Different Surfactants Base Fluids

Author(s): Radwa A. El-Salamony*, Mohamed Z. Abd-Elaziz, Rania E. Morsi, Ahmed M. Al-Sabagh and Saad S.M. Hassan

Volume 10, Issue 5, 2020

Page: [682 - 695] Pages: 14

DOI: 10.2174/2210681209666190319151152

Price: $65

Abstract

Background: Improvement of conventional heat transfer fluids for achieving higher energy efficiencies in thermal equipment is a key parameter to conserve energy in industries. The heat transfer fluids such as water, oil and ethylene glycol greatly suffer low heat transfer performance in industrial processes. There is a need to develop new types of heat transfer fluids that are more effective in terms of heat transfer performance. Nanofluids enhance thermal conductivity and improve the thermal performance of heat transfer systems.

Methods: New titania nanofluid samples consisting of 0.0625 to 1% TiO2 nanoparticles were prepared and characterized. The method of preparation was based on prior precipitation of TiO2 from an ammoniacal solution of pH 9 and calcination at 900°C. Solubilization, homogenization and stabilization of the of the nanoparticles were performed by sonication in the presence of sodium dodecyl sulfate (SDS) anionic surfactant and cetyltrimethylammonium bromide (CTAB) cationic surfactant.

Results: This treatment was also utilized to increase the stability and improve the thermal properties of the fluid.

Conclusion: Several characterization techniques including measurements of hydrodynamic size distribution, zeta potential, transmission electron microscopy (TEM), viscosity, density, specific heat, thermal conductivity, and sedimentation photo capturing were used to measure and confirm the stability and sedimentation rate of the prepared nanofluids.

Keywords: Titanium nanofluids, rutile phase, CTAB, SDS, thermal properties, heat transfer performance.

Graphical Abstract

[1]
Sarit, K.D. Nanofluids-The Cooling Medium of the Future. Heat Transf. Eng., 2006, 27(10), 1-2.
[http://dx.doi.org/10.1080/01457630600904585]]
[2]
Elsalamony, R.A.; Morsi, R.E.; Alsabagh, A.M. Influence of gamma radiation on the improvement of stability, conductivity and photoactivity of titania nanofluid. J. Nanofluids, 2015, 4(4), 442-448.
[http://dx.doi.org/10.1166/jon.2015.1179]]
[3]
El-Salamony, R.A.; Morsi, R.E. Stable gallium oxide@silica/polyvinyl pyrrolidone hybrid nanofluids: Preparation, characterization, and photo-activity toward removal of malachite green dye. J. Mol. Liquids., 2018, 271, 589-598.DOI.org/10.1016/j.molliq.2018.08.139
[4]
Reddy, P.S.; Chamkha, A.J. Influence of size, shape, type of nanoparticles, type and temperature of the base fluid on natural convection MHD of nanofluids. Alexandria Eng. J., 2016, 55, 331-341.DOI.org/10.1016/j.aej.2016.01.027
[5]
Barzegarian, R.; Moraveji, M.K.; Aloueyan, A. Experimental investigation on heat transfer characteristics and pressure drop of BPHE (brazed plate heat exchanger) using TiO2–water nanofluid. Exp. Thermal. Fluid Sci., 2016, 74, 11-18.DOI.org/10.1016/j.expthermflusci.2015.11.018
[6]
Khedkar, R.S.; Shrivastava, N.; Sonawane, S.S.; Wasewar, K.L. Experimental investigations and theoretical determination of thermal conductivity and viscosity of TiO2–ethylene glycol nanofluid. Int. Commun. Heat Mass Transf., 2016, 73, 54-61.DOI.org/10.1016/j.icheatmasstransfer.2016.02.004
[7]
Sen, S.; Govindarajan, V.; Pelliccione, C.J.; Wang, J.; Mille, D.J.; Timofeeva, E.V. Surface modification approach to TiO2 nanofluids with high particle concentration, low viscosity, and electrochemical activity. ACS Appl. Mater. Interfaces, 2015, 7, 20538-20547.DOI.org/10.1021/acsami.5b05864
[8]
Mintsa, H.A.; Roy, G.; Nguyen, C.T.; Doucet, D. New temperature dependent thermal conductivity data for water-based nanofluids. Int. J. Therm. Sci., 2009, 48, 363-371.
[http://dx.doi.org/10.1016/j.ijthermalsci.2008.03.009]
[9]
He, Y.; Jin, Y.; Chen, H.; Ding, Y.; Cang, D.; Lu, H. Heat transfer and flow behavior of aqueous suspensions of TiO2 nanoparticles (nanofluids) flowing upward through a vertical pipe. Int. J. Heat Mass Transfer., 2007, 50(11), 2272-2281.
[http://dx.doi.org/10.1016/j.ijheatmasstransfer.2006.10.024]]
[10]
Lee, J-H.; Lee, S-H.; Jang, S.P. Do temperature and nanoparticle size affect the thermal conductivity of alumina nanofluids? Appl. Phys. Lett., 2014, 104(16), 1908.10.1063/1.4872164
[11]
Beck, M.P.; Yuan, Y.; Warrier, P.; Teja, A.S. The effect of particle size on the thermal conductivity of alumina nanofluids. J. Nanopart. Res., 2009, 11, 1129-1136.http://sci-hub.tw/10.1007/s11051-008-9500-2
[12]
Timofeeva, E.V.; Yu, W.; France, D.M.; Singh, D.; Routbort, J.L. Base fluid and temperature effects on the heat transfer characteristics of SiC in ethylene glycol/H2O and H2O nanofluids. J. Appl. Phys., 2011, 109, 014914.
[http://dx.doi.org/10.1063/1.3524274]]
[13]
Timofeeva, E.V.; Smith, D. S.; Yu, W.; France, D.M.; Singh, D.; Routbort, J.L. Particle size and interfacial effects on thermo-physical and heat transfe characteristics of water-based a-SiC nanofluids. Nanotechnology, 2010, 21, 215703.
[http://dx.doi.org/10.1088/0957-4484/21/21/215703]
[14]
Barbés, R.; Páramo, E.; Blanco, M.J.; Pastoriza-Gallego, M.M.; Piñeiro, J.L.; Legido, L.; Casanova, C. Thermal conductivity and specific heat capacity measurements of Al2O3 nanofluids. J. Therm. Anal. Calorim., 2013, 111, 1615-1625.http://sci-hub.tw/10.1007/s10973-012-2534-9
[15]
Vajjha, R.S.; Das, D.K. Specific heat measurement of three nanofluids and development of new correlations. J. Heat Transfer, 2009, 131(7), 071601.https://sci-hub.tw/10.1115/1.3090813
[16]
Yiamsawasd, T.; Dalkilic, A.S.; Wongwises, S. Measurement of specific heat of nanofluids. Curr. Nanosci., 2012, 8, 939-944.
[http://dx.doi.org/10.2174/157341312803989132]]
[17]
Sekhar, Y.R.; Sharma, K.V. Study of viscosity and specific heat capacity characteristics of water-based Al2O3 nanofluids at low particle concentrations. J. Exp. Nanosci., 2013, 10(2), 86-102.
[http://dx.doi.org/10.1080/17458080.2013.796595]]
[18]
Teng, T.P.; Hung, Y.H. Estimation and experimental study of the density and specific heat for alumina nanofluid. J. Exp. Nanosci., 2012, 9(7), 707-718.
[http://dx.doi.org/10.1080/17458080.2012.696219]
[19]
Aboul-Gheit, A.K.; El-Desouki, D.S.; El-Salamony, R.A. Different outlet for preparing nano-TiO2 catalysts for the photodegradation of Black B Dye in Water. Egypt. J. Petrol., 2014, 23, 339-348.
[http://dx.doi.org/10.1016/j.ejpe.2014.08.010]
[20]
Pfeiffer, C.; Rehbock, C.; Hüh, D.; Carrillo-Carrion, C.; Jimenez de Aberasturi, D.; Merk, V.; Barcikowski, S.; Parak, W.J. J. R. Soc. Interface, 2014, 11(96), 20130931.
[http://dx.doi.org/10.1098/rsif.2013.0931]
[21]
Verma, S.K.; Tiwari, A.K. Characterization of nanofluids as an advanced heat transporting medium for energy systems. Mater. Today Proc., 2017, 4(2), 4095-4103.
[http://dx.doi.org/10.1016/j.matpr.2017.02.313]
[22]
Trisaksri, V.; Wongwises, S. Critical review of heat transfer characteristics of the nanofluids. Renew. Sustain. Energy Rev., 2007, 11, 512-523.
[http://dx.doi.org/10.1016/j.rser.2005.01.010]
[23]
Wang, X-Q.; Mujumdar, A.S. Heat transfer characteristics of nanofluids: A review. Int. J. Therm. Sci., 2007, 46(1), 1-19.
[http://dx.doi.org/10.1016/j.ijthermalsci.2006.06.010]]
[24]
Paul, G.; Chopkar, M.; Manna, I.; Das, P.K. Techniques for measuring the thermal conductivity of nanofluids: A review. Renew. Sustain. Energy Rev., 2010, 14(7), 1913-1924.
[http://dx.doi.org/10.1016/j.rser.2010.03.017]]
[25]
Murshed, S.M.S.; Leong, K.C.; Yang, C. Thermophysical and electrokinetic properties of nanofluids – a critical review. Appl. Therm. Eng., 2008, 28(17-18), 2109-2125.
[http://dx.doi.org/10.1016/j.applthermaleng.2008.01.005]
[26]
`1Wang, X.-j.; Zhu, D.-S.; Yang, S. Investigation of pH and SDBS on enhancement of thermal conductivity in nanofluids. Chem. Phys. Lett., 2009, 470(1-3), 107-111.
[http://dx.doi.org/10.1016/j.cplett.2009.01.035]
[27]
Alawi, S.M. Thermodynamics studies of cetyltrimethylammonium bromide (CTAB) in N, N-dimethyl acetamide-water mixtures. Orient. J. Chem., 2010, 26(4), 1235-1240.
[28]
Anachkov, E.S.; Danov, K.D.; Bashev, E.S.; Kralchevsky, P.A.; Ananthapadmanabhan, K.P. Determination of the aggregation number and charge of ionic surfactant micelles from the stepwise thinning of foam films. Adv. Colloid Interface Sci., 2012, 55-67, 183-184.
[http://dx.doi.org/10.1016/j.cis.2012.08.003]]
[29]
Devendiran, D.K.; Amirtham, V.A. A review on preparation, characterization, properties and applications of nanofluids. Renew. Sustain. Energy Rev., 2016, 60, 21-40.
[http://dx.doi.org/10.1016/j.rser.2016.01.055]
[30]
Sommers, A.D.; Yerkes, K.L. Experimental investigation into the convective heat transfer and system-level effects of Al2O3 propanol nanofluids. J. Nanopart. Res., 2010, 12, 1003-1014.https://sci-hub.tw/10.1007/s11051-009-9657-3
[31]
Morîntale, E.; Harabor, A.; Constantinescu, C.; Rotaru, P. Use of heat flows from DSC curve for calculation of specific heat of the solid materials. Physics AUC, 2013, 23, 89-94.
[http://dx.doi.org/sci-hub.tw/10.1007/s11051-009-9657-3.]

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