Abstract
In this review we introduced many kinds of bifunctional N-substituted amides, including phosphinamides and phosphoramides, squaramides, sulfonamides and so on which were applied to the asymmetric reactions. More emphasis were given to the asymmetric borane reduction of prochiral ketones, the reaction conditions and mechanisms were discussed systematically. At the same time, other reactions, including asymmetric addition, Diels-Alder reaction and Aldol reactions catalyzed by chiral N-substituted amides were also reviewed.
Keywords: N-Substituted Amides, Chiral Ligands, squaramides
Current Organic Chemistry
Title: N-Substituted Amides as Chiral Ligands for Catalytic Asymmetric Reactions
Volume: 6 Issue: 10
Author(s): Ji Zhang, Hai-Bing Zhou and Ru-Gang Xie
Affiliation:
Keywords: N-Substituted Amides, Chiral Ligands, squaramides
Abstract: In this review we introduced many kinds of bifunctional N-substituted amides, including phosphinamides and phosphoramides, squaramides, sulfonamides and so on which were applied to the asymmetric reactions. More emphasis were given to the asymmetric borane reduction of prochiral ketones, the reaction conditions and mechanisms were discussed systematically. At the same time, other reactions, including asymmetric addition, Diels-Alder reaction and Aldol reactions catalyzed by chiral N-substituted amides were also reviewed.
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Cite this article as:
Zhang Ji, Zhou Hai-Bing and Xie Ru-Gang, N-Substituted Amides as Chiral Ligands for Catalytic Asymmetric Reactions, Current Organic Chemistry 2002; 6 (10) . https://dx.doi.org/10.2174/1385272023373806
DOI https://dx.doi.org/10.2174/1385272023373806 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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