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Nanoscience & Nanotechnology-Asia

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ISSN (Print): 2210-6812
ISSN (Online): 2210-6820

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Review Article

Using Low Temperature, Cost-effective and Green Methods to Carbon Nanohorn Synthesis

Author(s): Ali Hasani*

Volume 9, Issue 2, 2019

Page: [157 - 160] Pages: 4

DOI: 10.2174/2210681208666180321143945

Price: $65

Abstract

Background: Laser ablation method has high-yield and pure SWCNHs. On the other hand, arc discharge methods have low-cost production of SWCNHs. However, these techniques have more desirable features, they need special expertness to use high power laser or high current discharge that either of them produces very high temperature. As for the researches, the temperatures of these techniques are higher than 4727°C to vaporize the graphite. So, to become aware of the advantages of SWCNHs, it is necessary to find a new way to synthesize SWCNHs at a lower temperature. In other words, reaction field can be expandable at a moderate temperature. This paper reports a new way to synthesize SWCNHs at an extremely reduced temperature.

Methods: According to this study, the role of N2 is the protection of the copper holder supporting the graphite rod by increasing heat transfer from the holder. After the current of 70 A was supplied to the system, the temperature of graphite rod was raised to 1600°C. It is obvious that this temperature is somehow higher than the melting point of palladium, 1555°C, and much lower than graphite melting point, 3497°C.

Results: Based on the results, there are transitional precursors simultaneous with the SWCNHs. This composition can be created by distortion of the primary SWCNTs at the higher temperature. Subsequently, each SWCNTs have a tendency to be broken into individual horns. With increasing the concentration of the free horns, bud-like SWCNHs can be produced. Moreover, there are individual horns almost separated from the mass of single wall carbon nanohorns. This structure is not common in SWCNHs synthesized by the usual method such as arc discharge or laser ablation. Through these regular techniques, SWCNHs are synthesized as cumulative particles with diameters about 30-150 nm.

Conclusion: A simple heating is needed for SWCNTs transformation to SWCNHs with the presence of palladium as catalyst. The well-thought-out mechanism for this transformation is that SWCNTs were initially changed to highly curled shape, and after that were formed into small independent horns. The other rout to synthesize SWCNHs is the pyrolysis of palm olein at 950°C with the assistance of zinc nitrate and ferrocene. Palm olein was used as a promising, bio-renewable and inexpensive carbon source for the production of carbon nanohorns.

Keywords: Carbon nanohorn, synthesis, arc-discharge, low temperature, SWCNHs, SWCNTs.

Graphical Abstract

[1]
Sano, N.; Ishii, T.; Tamon, H. Transformation from single-walled carbon nanotubes to nanohorns by simple heating with Pd at 1600°C. Carbon, 2011, 49(11), 3698-3700.
[2]
Zobir, S.A.M.; Zainal, Z.; Keng, C.S.; Sarijo, S.H.; Yusop, M. Synthesis of carbon nanohorn-carbon nanotube hybrids using palm olein as a precursor. Carbon, 2013, 54, 492-494.
[3]
Ghosh, P.; Soga, T.; Ghosh, K.; Afre, R.A.; Jimbo, T.; Ando, Y. Vertically aligned N-doped carbon nanotubes by spray pyrolysis of turpentine oil and pyridine derivative with dissolved ferrocene. J. Non-Cryst. Solids, 2008, 354, 4101.
[4]
Irie, M.; Nakamura, M.; Zhang, M.; Yuge, R.; Iijima, S.; Yudasaka, M. Quantification of thin graphene sheets contained in spherical aggregates of single-walled carbon nanohorns. Chem. Phys. Lett., 2010, 500, 96.
[5]
Kuang-Ting, H.; Sadeghian, R.; Gangireddy, S.; Minaie, B. Manufacturing carbon nanofibers toughened polyester/glass fiber composites using vacuum assisted resin transfer molding for enhancing the mode-I delamination resistance. Compos. A., 2006, 37(10), 1787-1795.
[6]
Li, H.; Zhao, N.; Wang, L.; Shi, C.; Du, X.; Li, J. Synthesis of carbon nanohorns by the simple catalytic method. J. Alloys Compd., 2009, 473, 288.
[7]
Li, Y.; Hori, N.; Arai, M.; Hu, N.; Liu, Y.; Fukunaga, H. Improvement of interlaminar mechanical properties of CFRP laminates using VGCF. Compos. A, 2009, 40(12), 2004-2012.
[8]
Li, N.; Wang, Z.; Zhao, K.; Shi, Z.; Gu, Z.; Xu, S. Synthesis of single wall carbon nanohorns by arc-discharge in air and their formation mechanism. Carbon, 2010, 48, 1580.
[9]
Lim, C-S.; Rodriguez, A.J.; Guzman, M.E.; Schaefer, J.D.; Minaie, B. Processing and properties of polymer composites containing aligned functionalized carbon nanofibers. Carbon, 2011, 49(6), 1873-1883.
[10]
Sarkar, S.; Das, P.K.; Bysakh, S. Effect of heat treatment on morphology and thermal decomposition kinetics of multiwalled carbon nanotubes. Mater. Chem. Phys., 2011, 125, 161.
[11]
Rodriguez, A.J.; Guzman, M.E.; Lim, C-S.; Minaie, B. Mechanical properties of carbon nanofiber/fiber-reinforced hierarchical composites manufactured with multiscale-reinforcement fabrics. Carbon, 2011, 49(3), 937-948.
[12]
Iijima, S.; Yudasaka, M.; Yamada, R.; Bandow, S.; Suenaga, K.; Kokai, F.; Takahashic, K. Nano-aggregates of single-walled graphitic carbon nanohorns. Chem. Phys. Lett., 1999, 309(3-4), 165-170.
[13]
Garcia, E.J.; Wardle, B.L.; Hart, J.A.; Yamamoto, N. Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown In situ. Compos. Sci. Technol., 2008, 68(9), 2034-2041.
[14]
Sano, N.; Nakano, J.; Kanki, T. Synthesis of single-walled carbon nanotubes with nanohorns by arc in liquid nitrogen. Carbon, 2004, 42(3), 686-688.
[15]
Fan, Z.; Santare, M.H.; Advani, S.G. Interlaminar shear strength of glass fiber reinforced epoxy composites enhanced with multiwalled carbon nanotubes. Compos. A., 2008, 39(3), 540-554.
[16]
Sano, N. Low-cost synthesis of single-walled carbon nanohorns using the arc in water method with gas injection. J. Phys. D Appl. Phys., 2004, 37(8), L17-L20.
[17]
Tibbetts, G.G.; Lake, M.L.; Strong, K.L.; Rice, B.P. A review of the fabrication and properties of vapor-grown carbon nanofiber/polymer composites. Compos. Sci. Technol., 2007, 67(7-8), 1709-1718.
[18]
Zobir, S.A.M.; Suriani, A.A.; Abdullah, S.; Zainal, Z.; Sarijo, S.H.; Rusop, M. Raman spectroscopic study of carbon nanotubes prepared using Fe/ZnO-palm plein-chemical vapour deposition. J. Nanomater., 2012.451473
[19]
Li, N.; Wang, Z.; Zhao, K.; Shi, Z.; Gu, Z.; Xu, S. Synthesis of single wall carbon nanohorns by arc-discharge in air and their formation mechanism. Carbon, 2010, 48(5), 1580-1585.
[20]
Bandow, S.; Kokai, F.; Takahashi, K.; Yudasaka, M.; Qin, L.C.; Iijima, S. Interlayer spacing anomaly of single-wall carbon nanohorn aggregate. Chem. Phys. Lett., 2000, 321, 514.
[21]
Yudasaka, M.; Ichihashi, T.; Kasuya, D.; Kataura, H.; Iijima, S. Structure changes of single-wall carbon nanotubes and singlewall carbon nanohorns caused by heat treatment. Carbon, 2003, 41(6), 1273-1280.
[22]
Glover, B.; Whites, K.W.; Hong, H.; Mukherjee, A.; Billups, W.E. Effective electrical conductivity of functional single-wall carbon nanotubes in aqueous fluids. Synth. Met., 2008, 158, 506.
[23]
Rachmadini, Y.; Tan, V.B.C.; Tay, T.E. Enhancement of mechanical properties of composites through incorporation of CNT in VARTM: A review. J. Reinf. Plast. Compos., 2010, 29(18), 2782-2807.
[24]
Sawant, S.Y.; Somani, R.S.; Bajaj, H.C. A solvothermal-reduction method for the production of horn shaped multi-wall carbon nanotubes. Carbon, 2010, 48, 668.
[25]
Zobir, S.A.M.; Abdullah, S.; Zainal, Z.; Sarijo, S.H.; Rusop, M. Synthesis of carbon nano- and microspheres using palm olein as the carbon source. Mater. Lett., 2012, 78, 205.
[26]
Marvin, B.; Dow, H.; Dexter, B. Development of stitched, braided and woven composite structures in the ACT program and at Langley Research Center. Hampton, Virginia; NASA/TP- 97-206234; 1997.
[27]
Takikawa, H.; Ikeda, M.; Hirahara, K.; Hibi, Y.; Tao, Y.; Ruiz, P.A., Jr Sakakibara, Itoh, S.; Iijim, S. Fabrication of single-walled carbon nanotubes and nanohorns by means of torch arc in open air. Phys. B., 2002, 323(1-4), 277-279.
[28]
Aoki, Y.; Urita, K.; Noguchi, D.; Itoh, T.; Kanoh, H.; Ohba, T.; Yudasaka, M.; Iijima, S.; Kaneko, K. Efficient production of H2 and carbon nanotube from CH4 over single wall carbon nanohorn. Chem. Phys. Lett., 2009, 482, 269.

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