Study on the Fluorine-Containing Reactive Intermediates and Their Application in the Organic Synthesis

Title: Study on the Fluorine-Containing Reactive Intermediates and Their Application in the Organic Synthesis

Volume: 8 Issue: 2

Author(s): S. Z. Zhu and P. He

Affiliation:

Keywords: Fluorine, phenyliodonium, polyfluorophenylaniline, N-sulfinyl

Abstract: This review deals with recent progress concerning the preparations, reactions, mechanisms and synthetic applications of some precursor compounds of the fluorine-containing reactive intermediates, such as phenyliodonium bis (perfluoro alkanesulfonyl) methides, PhI+--C(SO2Rf)2; perfluoroalkanesulfonyl azides, RfSO2N3 N,N-dichloro perfluoroalkanesulfonyl amides, RfSO2NCl2, aryldiazonium bis(perfluoro alkanesulfonyl) methides, ArN2 +--CH(SO2Rf)2, aryldiazonium bis(perfluoroalkanesulfonyl) imides, ArN2 +--N(SO2Rf)2 N-sulfinyl per- (or) polyfluoroalkanesulfonyl amides, RfSO2N=S=O, N-sulfinyl per- (or) polyfluorophenylaniline, ArFN=S=O. Under mild reaction conditions they react readily with many organic reagents to give various fluorine-containing products.

Cite this article as:

Zhu Z. S. and He P., Study on the Fluorine-Containing Reactive Intermediates and Their Application in the Organic Synthesis, Current Organic Chemistry 2004; 8 (2) . https://dx.doi.org/10.2174/1385272043486034