Abstract
Heterogeneous catalysis using sole metal-organic frameworks (MOFs) remains an immature field because these MOFs have insufficient active sites. The “inorganic effect” allows MOFs to become solid supports to immobilize polyoxometalates and metal nanoparticles, whereas the “organic effect” enables MOFs to function with organic groups such as -NH2 and -SO3H. These functionalized MOFs can be applied in various reactions, such as oxidation, hydrogenation, Knoevenagel condensation, dehydration, and hydrolysis. This review presents the catalytic transformation of organic molecules and biomass derivatives with MOFs.
Keywords: Multi-catalysis, MOFs, organic synthesis, biomass conversion.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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