Abstract
The reactions of sulfur ylides with carbonyl, olefin or imine compounds named as the Corey- Chaykovsky, provide oxiranes, cyclopropane or aziridine, respectively. In this report, we try to introduce this important name reaction and highlight a comprehensive overview on the applications of this useful reaction in synthetic organic chemistry and total synthesis of natural products.
Keywords: Corey-Chaykovsky, epoxidation, dimethylsulfoxonium methylide, dimethylsulfonium methylide, organic and total synthesis.
Current Organic Synthesis
Title:Developments of Corey-Chaykovsky in Organic Reactions and Total Synthesis of Natural Products
Volume: 13 Issue: 3
Author(s): Majid M. Heravi, Shima Asadi, Niousha Nazari and Boshra Malekzadeh Lashkariani
Affiliation:
Keywords: Corey-Chaykovsky, epoxidation, dimethylsulfoxonium methylide, dimethylsulfonium methylide, organic and total synthesis.
Abstract: The reactions of sulfur ylides with carbonyl, olefin or imine compounds named as the Corey- Chaykovsky, provide oxiranes, cyclopropane or aziridine, respectively. In this report, we try to introduce this important name reaction and highlight a comprehensive overview on the applications of this useful reaction in synthetic organic chemistry and total synthesis of natural products.
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Cite this article as:
M. Heravi Majid, Asadi Shima, Nazari Niousha and Malekzadeh Lashkariani Boshra, Developments of Corey-Chaykovsky in Organic Reactions and Total Synthesis of Natural Products, Current Organic Synthesis 2016; 13 (3) . https://dx.doi.org/10.2174/1570179412666150710182304
DOI https://dx.doi.org/10.2174/1570179412666150710182304 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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