Abstract
This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.
Keywords: walsh model, cyclopropene chemistry, carbometallation, electrophiles, alkylzinc addition, grignard reagents, cyclopropylbutyrolactones, natural products synthesis, hydroboration
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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