Abstract
This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.
Keywords: walsh model, cyclopropene chemistry, carbometallation, electrophiles, alkylzinc addition, grignard reagents, cyclopropylbutyrolactones, natural products synthesis, hydroboration
Current Organic Chemistry
Title: Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes
Volume: 9 Issue: 7
Author(s): Joseph M. Fox and Ni Yan
Affiliation:
Keywords: walsh model, cyclopropene chemistry, carbometallation, electrophiles, alkylzinc addition, grignard reagents, cyclopropylbutyrolactones, natural products synthesis, hydroboration
Abstract: This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.
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Cite this article as:
Fox M. Joseph and Yan Ni, Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes, Current Organic Chemistry 2005; 9 (7) . https://dx.doi.org/10.2174/1385272053765006
DOI https://dx.doi.org/10.2174/1385272053765006 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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