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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Molecular Complexes of Monoammonium Glycyrrhizinate with Alphahederin and Hederasaponin C

Author(s): Leonid A. Yakovishin, Vladimir I. Grishkovets and Elena N. Korzh

Volume 12, Issue 2, 2015

Page: [109 - 114] Pages: 6

DOI: 10.2174/1570178612666141230234729

Price: $65

Abstract

Molecular complexes of monoammonium glycyrrhizinate (glycyram) with triterpene glycosides from ivy alpha- hederin (hederagenin 3-O-α-L-rhamnopyranosyl-(1→2)2)-O-α-L-arabinopyranoside) and hederasaponin C (hederagenin 3-O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranosyl-28-0-α-L-rhamnopyranosyl-(1→4)-0-β-D-glucopyranosyl-( 1→6)-0-β-D-glucopyranoside) have been prepared for the first time. The complexation has been investigated by FT-IR and UV spectroscopy. The glycosides form complexes in the 1:1 molar ratio. The allelopathic activity and ichthyotoxicity of the molecular complexes have been considered.

Keywords: Alpha-hederin, hederasaponin C, monoammonium glycyrrhizinate, molecular complex.

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