Abstract
Nafion-H®, a perfluoroalkanesulfonic acid resin has emerged as one of the promising and potential heterogeneous catalysts. It has been widely applied as a green, efficient and a recyclable heterogeneous solid acid catalyst in diverse organic synthesis. The present review highlights the significant advancements which have been made in the last few decades in the field of Nafion-H® catalyzed organic reactions of synthetic relevance. This review mainly focuses on the utility of Nafion-H® catalyst for construction of carbon-carbon, carbon-oxygen bonds, oxidation reactions, protection and deprotection of alcohols and carbonyl compounds, functional group transformations, synthesis of heterocycles, rearrangements and some functionalized derivatives of Nafion-H®.
Keywords: Heterogeneous catalysis, Nafion-H®, organic synthesis.
Graphical Abstract
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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