Abstract
In this review, a group of two-dimensional (2D) self-assembled supramolecular chemical reactions observed by our laboratory are discussed. Our focuses mainly involve: 1) Surface supramolecular chemical reactions tuned by photo-stimulation; 2) Regulation of surface-confined nanostructure with metal-ligand coordination; 3) Construction of 2D supramolecular nanostructures through Schiff-base reaction observed by STM. It is envisioned that studies on these reactions are beneficial for us to understand the mechanism of supramolecular self-assembly process and impose further control over them.
Keywords: Scanning tunneling microscopy (STM), supramolecular self-assembly, In-situ surface chemical reactions.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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