Abstract
The review summarizes the use of metal nanoparticles as catalysts in cross-coupling reactions. Nanoparticle-sized catalysts are used in a variety of reactions, however, this chapter will focus on their use in the following cross-coupling reactions: Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, Ullmann and Stille. Catalysts in nanoparticle size are often supported on other materials, referred to as catalyst supports. The various catalyst supports utilized for nanoparticles used in cross-coupling reactions will also be presented.
Keywords: Nanoparticles, catalysis, palladium, copper, cross-coupling reactions, Suzuki-Miyaura reaction, Mizoroki-Heck reaction, Sonogashira reaction, Ullmann reaction, Stille reaction.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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