Salicylaldoxime-Supported Nona- and Tetrametallic Fe^III Cages

Title:Salicylaldoxime-Supported Nona- and Tetrametallic Fe^III Cages

Volume: 3 Issue: 2

Author(s): Kevin Mason, Alessandro Prescimone, Magnus Schau-Magnussen, Stergios Piligkos, Peter A. Tasker and Euan K. Brechin

Affiliation:

Keywords: Fe^III coordination compounds, salicylaldoxime ligands, X-ray crystallography, SQUID magnetometry.

Abstract: The syntheses, structures and magnetic properties of seven new iron complexes, [Fe₄O₂(sao)₄(tacn)₂]·2MeOH·H₂O (1·2MeOH·H₂O), [Fe₄O₂(Me-sao)₄(tacn)₂]·2MeCN (2·2MeCN), [Fe₄O₂(Etsao) ₄(tacn)₂]·MeOH (3·MeOH), [Fe₉NaO₄(Et-sao)₆(hmp)₈]·3MeCN·Et2O (4·3MeCN·Et₂O), [Fe₄(Et-sao)₄(hmp)₄]·Et-saoH₂ (5·Et-saoH₂), [Fe₄(Ph-sao)₄(hmp)₄]·2MeCN (6·2MeCN) [Fe₉O₃(sao)(pdm)₆(N₃)₇(H₂O)] (7), stabilised with salicylaldoxime (saoH₂) or derivatised salicylaldoxime (R-saoH₂) ligands in conjunction with either 1,4,7-triazocyclononane (tacn), 2-(hydroxymethyl)pyridine (hmpH) or 2,6-pyridinedimethanol (pdmH₂) are discussed.

Cite this article as:

Mason Kevin, Prescimone Alessandro, Schau-Magnussen Magnus, Piligkos Stergios, Tasker A. Peter and Brechin K. Euan, Salicylaldoxime-Supported Nona- and Tetrametallic Fe^III Cages, Current Inorganic Chemistry (Discontinued) 2013; 3 (2) . https://dx.doi.org/10.2174/1877944111303020002

DOI https://dx.doi.org/10.2174/1877944111303020002	Print ISSN 1877-9441
Publisher Name Bentham Science Publisher	Online ISSN 1877-945X