Abstract
The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.
Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.
Current Organic Chemistry
Title:Synthesis of a Rigid Fused Porphyrin-Phthalocyanine Hetero-Dyad with Two Different Metals
Volume: 17 Issue: 10
Author(s): Mario J.F. Calvete, Joao P.C. Tome and Jose A.S. Cavaleiro
Affiliation:
Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.
Abstract: The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.
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Cite this article as:
Calvete Mario J.F., Tome Joao P.C. and Cavaleiro Jose A.S., Synthesis of a Rigid Fused Porphyrin-Phthalocyanine Hetero-Dyad with Two Different Metals, Current Organic Chemistry 2013; 17 (10) . https://dx.doi.org/10.2174/1385272811317100010
DOI https://dx.doi.org/10.2174/1385272811317100010 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Chemistry and Biology of Carbohydrates
Carbohydrates are one of the most abundant natural products and are considered to be extremely important biomolecules for their ever-increasing impact on chemistry and biology. Their role in several important biological processes, notably energy storage, transport, modulation of protein function, intercellular adhesion, malignant transformation, signal transduction, viral, and bacterial cell ...read more
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