Abstract
Silica functionalized with both ammonium and vinyl groups had been synthesized. By using the functionalized silica as a support, an immobilized platinum catalyst had been prepared and its catalytic properties in the hydrosilylation of alkenes had been investigated. Excellent catalytic performance was observed in the hydrosilylation of alkenes with triethoxysilane. The supported catalyst could be reused several times without any obvious loss of catalytic activity.
Keywords: Alkenes, functionalized, hydrosilylation, platinum, silica, platinum complexes, MCM-41, siloxane, tetradecene, Triethoxysilane, toluene, amino-silica, chloroplatinic acid
Current Catalysis
Title:Functionalized Silica Immobilized Platinum Catalyst and Its Application in the Catalytic Hydrosilylation of Alkenes
Volume: 1 Issue: 3
Author(s): Ying Bai, Jiajian Peng, Jiayun Li, Guoqiao Lai and Xiaonian Li
Affiliation:
Keywords: Alkenes, functionalized, hydrosilylation, platinum, silica, platinum complexes, MCM-41, siloxane, tetradecene, Triethoxysilane, toluene, amino-silica, chloroplatinic acid
Abstract: Silica functionalized with both ammonium and vinyl groups had been synthesized. By using the functionalized silica as a support, an immobilized platinum catalyst had been prepared and its catalytic properties in the hydrosilylation of alkenes had been investigated. Excellent catalytic performance was observed in the hydrosilylation of alkenes with triethoxysilane. The supported catalyst could be reused several times without any obvious loss of catalytic activity.
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Cite this article as:
Bai Ying, Peng Jiajian, Li Jiayun, Lai Guoqiao and Li Xiaonian, Functionalized Silica Immobilized Platinum Catalyst and Its Application in the Catalytic Hydrosilylation of Alkenes, Current Catalysis 2012; 1 (3) . https://dx.doi.org/10.2174/2211544711201030180
DOI https://dx.doi.org/10.2174/2211544711201030180 |
Print ISSN 2211-5447 |
Publisher Name Bentham Science Publisher |
Online ISSN 2211-5455 |
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