Diphenyl-2-Pyridylphosphine Based Palladium Catalysts for the Suzuki- Miyaura Reactions in Environment Friendly Solvents

Archana      Tairai; Nasifa      Shahnaz; Chandan      Sarmah; Pankaj      Das

doi:10.2174/157017812802139690

Abstract

Three palladium complexes derived from diphenyl-2-pyridylphosphine (PPh2Py) were investigated for their utility as catalysts for the Suzuki-Miyaura reactions of aryl halides in environment friendly solvents such as water, alcohols etc. Good-to-excellent yields of coupling products were achieved with a wide range of aryl halides under mild reaction conditions.

Keywords: Aqueous condition, diphenyl-2-pyridylphosphine, hemilabile ligand, palladium catalyst, room temperature, suzuki-miyaura reaction, biphenyl-type phosphine, phosphapalladacycles, bidentate phosphine, arylboronic, P-monodentate

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Letters in Organic Chemistry

Title:Diphenyl-2-Pyridylphosphine Based Palladium Catalysts for the Suzuki- Miyaura Reactions in Environment Friendly Solvents

Volume: 9 Issue: 7

Author(s): Archana Tairai, Nasifa Shahnaz, Chandan Sarmah and Pankaj Das

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Abstract: Three palladium complexes derived from diphenyl-2-pyridylphosphine (PPh2Py) were investigated for their utility as catalysts for the Suzuki-Miyaura reactions of aryl halides in environment friendly solvents such as water, alcohols etc. Good-to-excellent yields of coupling products were achieved with a wide range of aryl halides under mild reaction conditions.

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Tairai Archana, Shahnaz Nasifa, Sarmah Chandan and Das Pankaj, Diphenyl-2-Pyridylphosphine Based Palladium Catalysts for the Suzuki- Miyaura Reactions in Environment Friendly Solvents, Letters in Organic Chemistry 2012; 9 (7) . https://dx.doi.org/10.2174/157017812802139690