Synthesis of (+)-(4S,5S)-Muricatacin via Pd-Catalyzed Stereospecific Hydroxy Substitution Reaction of γ,δ-epoxy α,β-Unsaturated Ester with B(OH)3

Title:Synthesis of (+)-(4S,5S)-Muricatacin via Pd-Catalyzed Stereospecific Hydroxy Substitution Reaction of γ,δ-epoxy α,β-Unsaturated Ester with B(OH)3

Volume: 9 Issue: 5

Author(s): Gowravaram Sabitha, G. Chandrashekhar, D. Vasudeva Reddy and J. S. Yadav

Affiliation:

Keywords: γ-Lactone, Pd-catalyzed, γ, δ-epoxy α, β-unsaturated ester, muricatacin, stereospecific, oxidation, pesticidal activities, hydrogenation, palladium

Abstract: The stereoselective synthesis of (+)-(4S,5S)-muricatacin has been achieved involving the palladium-catalyzed stereospecific hydroxy substitution reaction of γ,δ-epoxy α,β-unsaturated ester with B(OH)3.

Cite this article as:

Sabitha Gowravaram, Chandrashekhar G., Vasudeva Reddy D. and S. Yadav J., Synthesis of (+)-(4S,5S)-Muricatacin via Pd-Catalyzed Stereospecific Hydroxy Substitution Reaction of γ,δ-epoxy α,β-Unsaturated Ester with B(OH)3, Letters in Organic Chemistry 2012; 9 (5) . https://dx.doi.org/10.2174/157017812801264656