Abstract
A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.
Keywords: Xestodecalactone B and C, Chiral pool, Intramolecular acylation, Hydroboration, Pinnick oxidation, Revision of absolute configuration
Current Organic Chemistry
Title:A Carbohydrate Based Total Synthesis of Xestodecalactone B and C: Revision of the Absolute Configuration
Volume: 16 Issue: 9
Author(s): Rita Pal, Hasibur Rahaman and Mukund K. Gurjar
Affiliation:
Keywords: Xestodecalactone B and C, Chiral pool, Intramolecular acylation, Hydroboration, Pinnick oxidation, Revision of absolute configuration
Abstract: A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.
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Cite this article as:
Pal Rita, Rahaman Hasibur and K. Gurjar Mukund, A Carbohydrate Based Total Synthesis of Xestodecalactone B and C: Revision of the Absolute Configuration, Current Organic Chemistry 2012; 16 (9) . https://dx.doi.org/10.2174/138527212800564321
DOI https://dx.doi.org/10.2174/138527212800564321 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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