Abstract
The Suzuki cross-coupling reaction, which is commonly referred to simply as the “Suzuki reaction” and uses palladium as a catalyst, has become an efficient tool for constructing C–C bonds over the past two decades. This paper reviews recent advances in the use of this reaction with heterogeneous palladium catalysts. The heterogenization of homogeneous catalysts by incorporation into an inorganic support (silica, mainly) or an organic polymer is currently of one the hottest research topics. Although heterogeneous catalysts based on uncomplexed Pd(II) or Pd(0) deposited on an inorganic supports such as carbon, silica or a zeolite remain in wide use, new catalysts consisting of Pd(0) nanoparticles entrapped in or deposited onto an organic or inorganic support are being increasingly used in the Suzuki reaction.
Keywords: Suzuki reaction, Cross-coupling reaction, Pd heterogenous catalysts
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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