Abstract
This updated version of a 2008 review presents work in the still developing field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus–element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P–P and P–E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.
Keywords: Dehydrocoupling, Phosphine, Heterodehydrocoupling, Bond-forming, Catalysis, Transition metal, micron-scale, Filtration, dihydroxylation, Stoichiometric, C–C bond activation, arylrhodium, stereoselectivities, tohormones
Call for Papers in Thematic Issues
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Chemistry and Biology of Carbohydrates
Carbohydrates are one of the most abundant natural products and are considered to be extremely important biomolecules for their ever-increasing impact on chemistry and biology. Their role in several important biological processes, notably energy storage, transport, modulation of protein function, intercellular adhesion, malignant transformation, signal transduction, viral, and bacterial cell ...read more
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