Iron-Catalyzed Oxidative Coupling of Terminal Alkynes with Arylboronic Acids

Xiu L. You, Lai Xu, Tao Hu

doi:10.2174/157017812800233688

Abstract

Iron-catalyzed cross-coupling of terminal alkynes with arylboronic acids under mild conditions has been developed. Although the reaction gave only moderate yields, the advantage of this method was its use of convenient and inexpensive iron catalyst.

Keywords: Arylboronic acids, iron catalyst, terminal alkynes, trimethoxysilanes, palladium/silver-catalyzed, methylphenylacetylene, electron-deficient groups, inorganic bases, carboxyl, fluoro

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Letters in Organic Chemistry

Title:Iron-Catalyzed Oxidative Coupling of Terminal Alkynes with Arylboronic Acids

Volume: 9 Issue: 4

Author(s): Xiu L. You, Lai Xu, Tao Hu

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Keywords: Arylboronic acids, iron catalyst, terminal alkynes, trimethoxysilanes, palladium/silver-catalyzed, methylphenylacetylene, electron-deficient groups, inorganic bases, carboxyl, fluoro

Abstract: Iron-catalyzed cross-coupling of terminal alkynes with arylboronic acids under mild conditions has been developed. Although the reaction gave only moderate yields, the advantage of this method was its use of convenient and inexpensive iron catalyst.

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Xiu L. You, Lai Xu, Tao Hu , Iron-Catalyzed Oxidative Coupling of Terminal Alkynes with Arylboronic Acids , Letters in Organic Chemistry 2012; 9 (4) . https://dx.doi.org/10.2174/157017812800233688