Abstract
A series of optically active β-aryloxy alcohols and β-arylthiol alcohols were synthesized directly by asymmetric transfer hydrogenation of the corresponding β-carbonyl ethers or β-carbonyl sulfides in excellent yields (up to 99%) and excellent enantioselectivity (up to 100% ee) under mild reaction conditions.
Keywords: Asymmetric transfer hydrogenation, β-aryloxy alcohols, β-arylthiol alcohols, β-ketosulfide, β-ketoether, esters, hydrogen, ketones, phenylethanone, sulfides