Diazaphospholane as an Efficient Ligand for Copper-Catalyzed Cross-Coupling of Thiols with Aryl Iodides

Minghua      Yang; Ji      Pei; Guobing      Yan; Yunfa      Zheng

doi:10.2174/157017811797249335

Abstract

Copper-catalyzed cross-coupling of thiols with aryl iodides performed well using an air-stable diazaphospholane ligand in presence of NaOH in DMF at 110 °C and a variety of diaryl sulfides are synthesized in good yields.

Keywords: Arylation, copper, cross-coupling, diazaphospholane, thiols, aryl iodides, aryl sulfides, L-proline, dimethylethylenediamine, dimethylglyoxime

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Letters in Organic Chemistry

Title: Diazaphospholane as an Efficient Ligand for Copper-Catalyzed Cross-Coupling of Thiols with Aryl Iodides

Volume: 8 Issue: 8

Author(s): Minghua Yang, Ji Pei, Guobing Yan and Yunfa Zheng

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Keywords: Arylation, copper, cross-coupling, diazaphospholane, thiols, aryl iodides, aryl sulfides, L-proline, dimethylethylenediamine, dimethylglyoxime

Abstract: Copper-catalyzed cross-coupling of thiols with aryl iodides performed well using an air-stable diazaphospholane ligand in presence of NaOH in DMF at 110 °C and a variety of diaryl sulfides are synthesized in good yields.

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Yang Minghua, Pei Ji, Yan Guobing and Zheng Yunfa, Diazaphospholane as an Efficient Ligand for Copper-Catalyzed Cross-Coupling of Thiols with Aryl Iodides, Letters in Organic Chemistry 2011; 8 (8) . https://dx.doi.org/10.2174/157017811797249335