Chiral Lewis Acid Catalysis in Water

Chikako      Ogawa; Shu      Kobayashi

doi:10.2174/157017911795529119

Abstract

The progress of development in chiral Lewis acid catalyzed reaction in water is described. Lewis acid surfactant-combined catalyst and chiral bipyridine ligand complex realized catalytic asymmetric hydroxymethylation and ring-opening reaction in water successfully. Furthermore, silica-supported Lewis acid catalyst was applied for asymmetric hydroxylation in water.

Keywords: Aldol reaction, Chiral Lewis acid, Epoxide, Green chemistry, Lewis acid, Mannich reaction, Water, asymmetric, organic, solvents

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Current Organic Synthesis

Title: Chiral Lewis Acid Catalysis in Water

Volume: 8 Issue: 3

Author(s): Chikako Ogawa and Shu Kobayashi

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Keywords: Aldol reaction, Chiral Lewis acid, Epoxide, Green chemistry, Lewis acid, Mannich reaction, Water, asymmetric, organic, solvents

Abstract: The progress of development in chiral Lewis acid catalyzed reaction in water is described. Lewis acid surfactant-combined catalyst and chiral bipyridine ligand complex realized catalytic asymmetric hydroxymethylation and ring-opening reaction in water successfully. Furthermore, silica-supported Lewis acid catalyst was applied for asymmetric hydroxylation in water.

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Ogawa Chikako and Kobayashi Shu, Chiral Lewis Acid Catalysis in Water, Current Organic Synthesis 2011; 8 (3) . https://dx.doi.org/10.2174/157017911795529119