Abstract
Stereoselective synthetic methods for the construction of the tertiary or quaternary asymmetric carbon centers having a trifluoromethyl group and carbon substituent(s) or hydrogen atom, not heteroatom substituent(s), are described.
Keywords: A direct stereoselective trifluoromethylation, building block methodology, diastereoselective, enantioselective, chiral, photochemical, organocatalyst