Homocoupling Reaction of Aryl Boronic Acids Catalyzed by Pd(OAc)2/K2CO3 in Water under Air Atmosphere

Nan      Wu; Xinnian      Li; Xin      Xu; Yumei      Wang,; Yunyun      Xu; Xi      Chen

doi:10.2174/157017810790534002

Abstract

Moderate to good yields of symmetrical biaryls were obtained under environmental friendly conditions via homocoupling reaction of aryl boronic acids catalyzed by Pd(OAc)2 / K2CO3 in water. Our method explores the synthetic utility of the homocoupling reaction of aryl boronic acids which may provide a simple and general alternative to the Suzuki reaction to achieve symmetrical biaryls.

Keywords: Aryl boronic acids, symmetrical biaryls, homocoupling reaction, environmental friendly reaction, water

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Letters in Organic Chemistry

Title: Homocoupling Reaction of Aryl Boronic Acids Catalyzed by Pd(OAc)2/K2CO3 in Water under Air Atmosphere

Volume: 7 Issue: 1

Author(s): Nan Wu, Xinnian Li, Xin Xu, Yumei Wang,, Yunyun Xu and Xi Chen

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Keywords: Aryl boronic acids, symmetrical biaryls, homocoupling reaction, environmental friendly reaction, water

Abstract: Moderate to good yields of symmetrical biaryls were obtained under environmental friendly conditions via homocoupling reaction of aryl boronic acids catalyzed by Pd(OAc)2 / K2CO3 in water. Our method explores the synthetic utility of the homocoupling reaction of aryl boronic acids which may provide a simple and general alternative to the Suzuki reaction to achieve symmetrical biaryls.

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Wu Nan, Li Xinnian, Xu Xin, Wang, Yumei, Xu Yunyun and Chen Xi, Homocoupling Reaction of Aryl Boronic Acids Catalyzed by Pd(OAc)2/K2CO3 in Water under Air Atmosphere, Letters in Organic Chemistry 2010; 7 (1) . https://dx.doi.org/10.2174/157017810790534002