Enantiodiscrimination by NMR Spectroscopy

Gloria      Uccello-Barretta; Federica      Balzano; Piero      Salvadori

doi:10.2174/138161206778743628

Abstract

The analysis of enantiorecognition processes involves the detection of enantiomeric species as well as the study of chiral discrimination mechanisms. In both fields Nuclear Magnetic Resonance (NMR) spectroscopy plays a fundamental role, providing several tools, based on the use of suitable chiral auxiliaries, for observing distinct signals of enantiomers and for investigating the complexation phenomena involved in enantiodiscrimination processes.

Keywords: Chiral Derivatizing Agents (CDAs), Selenium Reagents, Lanthanide ions, heterocomplexation, diastereoisomers

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Current Pharmaceutical Design

Title: Enantiodiscrimination by NMR Spectroscopy

Volume: 12 Issue: 31

Author(s): Gloria Uccello-Barretta, Federica Balzano and Piero Salvadori

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Keywords: Chiral Derivatizing Agents (CDAs), Selenium Reagents, Lanthanide ions, heterocomplexation, diastereoisomers

Abstract: The analysis of enantiorecognition processes involves the detection of enantiomeric species as well as the study of chiral discrimination mechanisms. In both fields Nuclear Magnetic Resonance (NMR) spectroscopy plays a fundamental role, providing several tools, based on the use of suitable chiral auxiliaries, for observing distinct signals of enantiomers and for investigating the complexation phenomena involved in enantiodiscrimination processes.

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Uccello-Barretta Gloria, Balzano Federica and Salvadori Piero, Enantiodiscrimination by NMR Spectroscopy, Current Pharmaceutical Design 2006; 12 (31) . https://dx.doi.org/10.2174/138161206778743628