A New Method for Halogenation of Aromatic Compounds By Using Dimethyldioxirane and Tetrabutylammonium Halides

Yean-Jang      Lee; Huan-Ting      Wu; Chia-Ning      Lin

doi:10.2174/157017809789869474

Abstract

In this presentation the novel regioselective halogenation of arenes or phenols with dimethyldioxirane and Bu4NX is described. The results showed that a new, versatile and mild method can be utilized for preparation of aryl halides starting with arenes or phenols. Finally, this aryl halide forming methodology is applicable to structurally more complex flavonoids.

Keywords: Dimethyldioxirane, regioselective halogenation, Bu4NX, flavonoids

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Letters in Organic Chemistry

Title: A New Method for Halogenation of Aromatic Compounds By Using Dimethyldioxirane and Tetrabutylammonium Halides

Volume: 6 Issue: 7

Author(s): Yean-Jang Lee, Huan-Ting Wu and Chia-Ning Lin

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Keywords: Dimethyldioxirane, regioselective halogenation, Bu4NX, flavonoids

Abstract: In this presentation the novel regioselective halogenation of arenes or phenols with dimethyldioxirane and Bu4NX is described. The results showed that a new, versatile and mild method can be utilized for preparation of aryl halides starting with arenes or phenols. Finally, this aryl halide forming methodology is applicable to structurally more complex flavonoids.

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Lee Yean-Jang, Wu Huan-Ting and Lin Chia-Ning, A New Method for Halogenation of Aromatic Compounds By Using Dimethyldioxirane and Tetrabutylammonium Halides, Letters in Organic Chemistry 2009; 6 (7) . https://dx.doi.org/10.2174/157017809789869474