Homogeneous CrVI-Catalyzed Benzylic, Allylic and Propargylic Oxidations by tert- Butyl Hydroperoxide

J.      Muzart

doi:10.2174/157019309787316120

Abstract

Environmental factors urge to use catalytic rather than stoichiometric oxidation methods. Over the last thirty years, we have reported a large panel of Cr-catalyzed oxidations. This mini-review concerns the benzylic, allylic and propargylic oxidations using CrVI catalysts and t-BuOOH under homogeneous conditions, and summarizes our results and those of the literature.

Keywords: Chromium oxides, tert-butyl hydroperoxide, catalysis, benzylic oxidation, allylic oxidation, propargylic oxidation, mechanism

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Mini-Reviews in Organic Chemistry

Title: Homogeneous CrVI-Catalyzed Benzylic, Allylic and Propargylic Oxidations by tert- Butyl Hydroperoxide

Volume: 6 Issue: 1

Author(s): J. Muzart

Affiliation:

Keywords: Chromium oxides, tert-butyl hydroperoxide, catalysis, benzylic oxidation, allylic oxidation, propargylic oxidation, mechanism

Abstract: Environmental factors urge to use catalytic rather than stoichiometric oxidation methods. Over the last thirty years, we have reported a large panel of Cr-catalyzed oxidations. This mini-review concerns the benzylic, allylic and propargylic oxidations using CrVI catalysts and t-BuOOH under homogeneous conditions, and summarizes our results and those of the literature.

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Muzart J., Homogeneous CrVI-Catalyzed Benzylic, Allylic and Propargylic Oxidations by tert- Butyl Hydroperoxide, Mini-Reviews in Organic Chemistry 2009; 6 (1) . https://dx.doi.org/10.2174/157019309787316120