PolyHIPEs as Novel Media for Conventional Free Radical Chemistry

Shengmiao      Zhang; Jianding      Chen; Victoria   T.   Perchyonok

doi:10.2174/157017808784049443

Abstract

The novel materials, polyHIPEs with incorporated tetrasubstituted ammonium cationic surfactant (CTAB) have been applied to a broad range of radical precursors in various free radical transformations in organic and aqueous media. The advantage of this reagent/ solid phase surfactant combination lies in its affordability, miniscule toxicity, avoidance of highly toxic “tin based hydrogen donors” under green reaction conditions.

Keywords: Free Radicals, PolyHIPEs as reaction media, synthesis, green chemistry

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Letters in Organic Chemistry

Title: PolyHIPEs as Novel Media for Conventional Free Radical Chemistry

Volume: 5 Issue: 4

Author(s): Shengmiao Zhang, Jianding Chen and Victoria T. Perchyonok

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Keywords: Free Radicals, PolyHIPEs as reaction media, synthesis, green chemistry

Abstract: The novel materials, polyHIPEs with incorporated tetrasubstituted ammonium cationic surfactant (CTAB) have been applied to a broad range of radical precursors in various free radical transformations in organic and aqueous media. The advantage of this reagent/ solid phase surfactant combination lies in its affordability, miniscule toxicity, avoidance of highly toxic “tin based hydrogen donors” under green reaction conditions.

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Zhang Shengmiao, Chen Jianding and Perchyonok T. Victoria, PolyHIPEs as Novel Media for Conventional Free Radical Chemistry, Letters in Organic Chemistry 2008; 5 (4) . https://dx.doi.org/10.2174/157017808784049443