An Efficient One-Pot, Two-Step Synthesis of Cyclobuxophyllinine M from Cyclovirobuxine D in Aqueous Media

Min      Ji; Hai-Feng      Liu; Xiao-Qing      Wu; Yan-Bing      Duan; Bin      Gu

doi:10.2174/157017808783743920

Abstract

A highly efficient one-pot, two-step sequential process consisting of modified Jones oxidation of aqueous cyclovirobuxine D acetate followed by Ruschig degradation after pH regulation with saturated aqueous NaOH, provided cyclobuxophyllinine M in high yield and in a single geometrical isomeric form.

Keywords: Jones oxidation, Ruschig degradation, cyclobuxophyllinine M, cyclovirobuxine D, aqueous media

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Letters in Organic Chemistry

Title: An Efficient One-Pot, Two-Step Synthesis of Cyclobuxophyllinine M from Cyclovirobuxine D in Aqueous Media

Volume: 5 Issue: 2

Author(s): Min Ji, Hai-Feng Liu, Xiao-Qing Wu, Yan-Bing Duan and Bin Gu

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Keywords: Jones oxidation, Ruschig degradation, cyclobuxophyllinine M, cyclovirobuxine D, aqueous media

Abstract: A highly efficient one-pot, two-step sequential process consisting of modified Jones oxidation of aqueous cyclovirobuxine D acetate followed by Ruschig degradation after pH regulation with saturated aqueous NaOH, provided cyclobuxophyllinine M in high yield and in a single geometrical isomeric form.

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Ji Min, Liu Hai-Feng, Wu Xiao-Qing, Duan Yan-Bing and Gu Bin, An Efficient One-Pot, Two-Step Synthesis of Cyclobuxophyllinine M from Cyclovirobuxine D in Aqueous Media, Letters in Organic Chemistry 2008; 5 (2) . https://dx.doi.org/10.2174/157017808783743920