Synthesis and Isomerization of 3-Pyrroline Enamines

A.   Gilbert   Cook; Karen   A.   Switek; Kenneth   A.   Cutler; Allison   M.   Witt

doi:10.2174/1570178043488734

Author(s): A. Gilbert Cook, Karen A. Switek, Kenneth A. Cutler and Allison M. Witt

Volume 1, Issue 1, 2004

Page: [1 - 5] Pages: 5

DOI: 10.2174/1570178043488734

Abstract

3-Pyrroline reacts with cyclic ketones to form enamines as kinetically controlled products. Under more vigorous conditions, pyrroles are formed as thermodynamically controlled products by way of a 1,3- hydride shift.

Keywords: enamine, pyrrole, isomerization, pyrroline

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Letters in Organic Chemistry

Title: Synthesis and Isomerization of 3-Pyrroline Enamines

Volume: 1 Issue: 1

Author(s): A. Gilbert Cook, Karen A. Switek, Kenneth A. Cutler and Allison M. Witt

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Keywords: enamine, pyrrole, isomerization, pyrroline

Abstract: 3-Pyrroline reacts with cyclic ketones to form enamines as kinetically controlled products. Under more vigorous conditions, pyrroles are formed as thermodynamically controlled products by way of a 1,3- hydride shift.

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Cook Gilbert A., Switek A. Karen, Cutler A. Kenneth and Witt M. Allison, Synthesis and Isomerization of 3-Pyrroline Enamines, Letters in Organic Chemistry 2004; 1 (1) . https://dx.doi.org/10.2174/1570178043488734