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Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Recent Advances in the Synthesis of P(III)-Chirogenic Compounds

Author(s): M. J. Johansson and N. C. Kann

Volume 1, Issue 3, 2004

Page: [233 - 247] Pages: 15

DOI: 10.2174/1570193043403235

Price: $65

Abstract

Chiral phosphorus(III) ligands with chirality residing on the phosphorus atom have seen a renaissance upon the discovery that coordination to boron stabilises the phosphorus atom towards both oxidation and racemization. In this review we describe the newer methods that are available for the preparation of P-chirogenic ligands and discuss their advantages and limitations.

Keywords: phosphorus, iigand, p-chirogenic, borane, chiral, asymmetric synthesis

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