Lactam-derived Vinyl Triflates and Phosphates in the Synthesis of N-heterocycles

Ernesto   G.   Occhiato

doi:10.2174/1570193043488890

Abstract

In the last decade there has been a growing interest in the coupling reactions of lactam-derived vinyl triflates and phosphates. The usefulness and versatility of these lactam derivatives in organic synthesis will be highlighted in this review that deals with the methods for their preparation, their stability and reactivity, and applications to the synthesis of natural compounds.

Keywords: catalysis, coupling, lactams, palladium, phosphates, triflates

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Mini-Reviews in Organic Chemistry

Title: Lactam-derived Vinyl Triflates and Phosphates in the Synthesis of N-heterocycles

Volume: 1 Issue: 2

Author(s): Ernesto G. Occhiato

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Keywords: catalysis, coupling, lactams, palladium, phosphates, triflates

Abstract: In the last decade there has been a growing interest in the coupling reactions of lactam-derived vinyl triflates and phosphates. The usefulness and versatility of these lactam derivatives in organic synthesis will be highlighted in this review that deals with the methods for their preparation, their stability and reactivity, and applications to the synthesis of natural compounds.

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Occhiato G. Ernesto, Lactam-derived Vinyl Triflates and Phosphates in the Synthesis of N-heterocycles, Mini-Reviews in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570193043488890