Synthesis of β-Ketonitriles from 3-Bromoisoxazoles

Martin   G.   Kociolek; Nicholas   G.   Straub; Elizabeth   J.   Marton

doi:10.2174/1570178053765302

Author(s): Martin G. Kociolek, Nicholas G. Straub and Elizabeth J. Marton

Volume 2, Issue 3, 2005

Page: [280 - 282] Pages: 3

DOI: 10.2174/1570178053765302

Price: $65

Abstract

A series of substituted 3-bromoisoxazoles were ring opened with either molybdenum hexacarbonyl or iron (II)chloride tetrahydrate to give β -ketonitriles in good yields.

Keywords: isoxazole, ketonitrile, molybdenum hexacarbonyl, ferrous chloride, reductive ring opening

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Letters in Organic Chemistry

Title: Synthesis of β-Ketonitriles from 3-Bromoisoxazoles

Volume: 2 Issue: 3

Author(s): Martin G. Kociolek, Nicholas G. Straub and Elizabeth J. Marton

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Keywords: isoxazole, ketonitrile, molybdenum hexacarbonyl, ferrous chloride, reductive ring opening

Abstract: A series of substituted 3-bromoisoxazoles were ring opened with either molybdenum hexacarbonyl or iron (II)chloride tetrahydrate to give β -ketonitriles in good yields.

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Kociolek G. Martin, Straub G. Nicholas and Marton J. Elizabeth, Synthesis of β-Ketonitriles from 3-Bromoisoxazoles, Letters in Organic Chemistry 2005; 2 (3) . https://dx.doi.org/10.2174/1570178053765302