Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

M.      Shimizu; S.      Itohara

doi:10.2174/157017805774296902

Abstract

An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enones gave 4-alkoxy-1,5-diketones in good yields.

Keywords: alkoxyacetone, alkoxyallene oxide, titanium tetraiodide, conjugate addition

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Letters in Organic Chemistry

Title: Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

Volume: 2 Issue: 7

Author(s): M. Shimizu and S. Itohara

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Keywords: alkoxyacetone, alkoxyallene oxide, titanium tetraiodide, conjugate addition

Abstract: An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enones gave 4-alkoxy-1,5-diketones in good yields.

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Shimizu M. and Itohara S., Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate, Letters in Organic Chemistry 2005; 2 (7) . https://dx.doi.org/10.2174/157017805774296902