Synthesis of meso-Aryl Substituted Porphyrins: Simple and High Yielding Modification of the Adler Procedure

Kamaljit Singh; Amit Sharma; Sonia Behal; Paramjit Kaur

doi:10.2174/157017807781212076

Abstract

An efficient single pot route is presented involving the use of O,N-perhydro 1,3-heterocycles as carbonyl equivalents for the synthesis of 5,5-disubstituteddipyrromethanes and meso-tetraarylporphyrins through a high yielding modified Adler route.

Keywords: Oxazinanes, dipyrromethanes, meso-porphyrins, perhydro 1,3-heterocycles, metalloporphyrins, carbonyl equivalents

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Letters in Organic Chemistry

Title: Synthesis of meso-Aryl Substituted Porphyrins: Simple and High Yielding Modification of the Adler Procedure

Volume: 4 Issue: 5

Author(s): Kamaljit Singh, Amit Sharma, Sonia Behal and Paramjit Kaur

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Keywords: Oxazinanes, dipyrromethanes, meso-porphyrins, perhydro 1,3-heterocycles, metalloporphyrins, carbonyl equivalents

Abstract: An efficient single pot route is presented involving the use of O,N-perhydro 1,3-heterocycles as carbonyl equivalents for the synthesis of 5,5-disubstituteddipyrromethanes and meso-tetraarylporphyrins through a high yielding modified Adler route.

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Kamaljit Singh , Amit Sharma , Sonia Behal and Paramjit Kaur , Synthesis of meso-Aryl Substituted Porphyrins: Simple and High Yielding Modification of the Adler Procedure, Letters in Organic Chemistry 2007; 4 (5) . https://dx.doi.org/10.2174/157017807781212076