MgI2 Etherate-Promoted Allylation of Aldehydes: Simple and Efficient Synthesis of Homoallylic Alcohols

Xingxian Zhang

doi:10.2174/157017807781024309

Volume 4, Issue 4, 2007

Page: [246 - 248] Pages: 3

DOI: 10.2174/157017807781024309

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Abstract

We describe a mild and efficient procedure for the synthesis of homoallylic alcohols using allyltributylstannane in the presence of MgI2 etherate (MgI2 .(OEt2)n) in good to excellent yields.

Keywords: Aldehydes, allyltributylstannane, homoallylic alcohol, MgI2 etherate

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Letters in Organic Chemistry

Title: MgI2 Etherate-Promoted Allylation of Aldehydes: Simple and Efficient Synthesis of Homoallylic Alcohols

Volume: 4 Issue: 4

Author(s): Xingxian Zhang

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Keywords: Aldehydes, allyltributylstannane, homoallylic alcohol, MgI2 etherate

Abstract: We describe a mild and efficient procedure for the synthesis of homoallylic alcohols using allyltributylstannane in the presence of MgI2 etherate (MgI2 .(OEt2)n) in good to excellent yields.

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Xingxian Zhang , MgI2 Etherate-Promoted Allylation of Aldehydes: Simple and Efficient Synthesis of Homoallylic Alcohols, Letters in Organic Chemistry 2007; 4 (4) . https://dx.doi.org/10.2174/157017807781024309