Stereoselective Addition of Chiral Oxazoline Cyanocuprates to Conjugated Nitroalkenes

Francisco   A.   Marques; Davi   C.   Silva; Edison   P.   Wendler; Celso   L.   Wosch; Quezia   B.   Cass; Fabiana      Batigalhia

doi:10.2174/157017807780737345

Abstract

Chiral oxazoline cyanocuprates were prepared and added to conjugated nitroalkenes. Stereoselectivity up to 80% was achieved with the cuprate prepared from the chiral oxazoline derived from (S)- Phenylalaninol.

Keywords: Chiral 2-oxazolines, cuprates, nitroalkenes, stereoselective addition

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Letters in Organic Chemistry

Title: Stereoselective Addition of Chiral Oxazoline Cyanocuprates to Conjugated Nitroalkenes

Volume: 4 Issue: 3

Author(s): Francisco A. Marques, Davi C. Silva, Edison P. Wendler, Celso L. Wosch, Quezia B. Cass and Fabiana Batigalhia

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Keywords: Chiral 2-oxazolines, cuprates, nitroalkenes, stereoselective addition

Abstract: Chiral oxazoline cyanocuprates were prepared and added to conjugated nitroalkenes. Stereoselectivity up to 80% was achieved with the cuprate prepared from the chiral oxazoline derived from (S)- Phenylalaninol.

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Marques A. Francisco, Silva C. Davi, Wendler P. Edison, Wosch L. Celso, Cass B. Quezia and Batigalhia Fabiana, Stereoselective Addition of Chiral Oxazoline Cyanocuprates to Conjugated Nitroalkenes, Letters in Organic Chemistry 2007; 4 (3) . https://dx.doi.org/10.2174/157017807780737345