Electrochemical Synthesis of Selenocarbonates

Alessandra      La Groia; Marta      Feroci; Achille      Inesi; Leucio      Rossi

doi:10.2174/157017806779117003

Abstract

Electrochemical reduction of diselenides allows the formation of selenide anions which react with different chloroformates yielding the corresponding selenocarbonates in moderate to very high yields. The reaction is general and prevents the use of further reagents or drastic reaction conditions. Moreover the use of labile or air sensitive precursors such as selenides is avoided.

Keywords: Selenocarbonates, electroorganic synthesis, reduction, diselenides, choloroformates

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Letters in Organic Chemistry

Title: Electrochemical Synthesis of Selenocarbonates

Volume: 3 Issue: 11

Author(s): Alessandra La Groia, Marta Feroci, Achille Inesi and Leucio Rossi

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Keywords: Selenocarbonates, electroorganic synthesis, reduction, diselenides, choloroformates

Abstract: Electrochemical reduction of diselenides allows the formation of selenide anions which react with different chloroformates yielding the corresponding selenocarbonates in moderate to very high yields. The reaction is general and prevents the use of further reagents or drastic reaction conditions. Moreover the use of labile or air sensitive precursors such as selenides is avoided.

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La Groia Alessandra, Feroci Marta, Inesi Achille and Rossi Leucio, Electrochemical Synthesis of Selenocarbonates, Letters in Organic Chemistry 2006; 3 (11) . https://dx.doi.org/10.2174/157017806779117003