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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Pre-Shaped Aromatic Picket Porphyrins Bearing Neutral Oxygen Donors and their Bismuth Complexes: Synthesis and Coordination Studies

Author(s): Lydie Michaudet, Zakaria Halime, Mohammed Lachkar and Bernard Boitrel

Volume 3, Issue 10, 2006

Page: [753 - 758] Pages: 6

DOI: 10.2174/157017806779025906

Price: $65

Abstract

Picket porphyrins delivering oxygen donor atoms borne by aromatic cycles around the sphere of coordination of bismuth cation have been studied for their ability to complex bismuth in a period of time not exceeding an hour. For this investigation, various structural features were considered: steric strength and length of the link between the aromatic cycle and the macrocyle core, nature and location of the oxygen atom(s) on the aromatic cycle.

Keywords: Bismuth coordination, porphyrin, kinetics, alpha emission


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