Hydroiodination of Terminal Double Bonds Via Hydroboration or Hydrozirconation in Connection with the Total Synthesis of Fluvirucins

Felix      Urpi; Jaume      Vilarrasa; Gloria      Freixas

doi:10.2174/157017806775789895

Abstract

Hydroboration and hydrozirconation of 4-pentenoic acid and 4-penten-1-ol derivatives, followed by iodination in situ, have been systematically compared for the first time, looking for chemoselective, regioselective (anti-Markovnikov), efficient conversions of these alkenes to key intermediates in the total syntheses of fluvirucins.

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Letters in Organic Chemistry

Title:Hydroiodination of Terminal Double Bonds Via Hydroboration or Hydrozirconation in Connection with the Total Synthesis of Fluvirucins

Volume: 3 Issue: 3

Author(s): Felix Urpi, Jaume Vilarrasa and Gloria Freixas

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Abstract: Hydroboration and hydrozirconation of 4-pentenoic acid and 4-penten-1-ol derivatives, followed by iodination in situ, have been systematically compared for the first time, looking for chemoselective, regioselective (anti-Markovnikov), efficient conversions of these alkenes to key intermediates in the total syntheses of fluvirucins.

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Urpi Felix, Vilarrasa Jaume and Freixas Gloria, Hydroiodination of Terminal Double Bonds Via Hydroboration or Hydrozirconation in Connection with the Total Synthesis of Fluvirucins, Letters in Organic Chemistry 2006; 3 (3) . https://dx.doi.org/10.2174/157017806775789895