New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens

Laurence      Bonnafoux; Nathalie      Nicod; Frederic      Leroux; Berengere      Quissac; Francoise      Colobert

doi:10.2174/157017806775224279

Abstract

Regioselective halogen/lithium permutation reactions were carried out on polybrominated biaryls. Thus, highly functionalized, dissymetrically substituted biaryls become easily accessible on gram scale.

Keywords: isoquinoline, halogen, polar organometallic methods, disproportionation, Complexation, chromatographic comparison

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Letters in Organic Chemistry

Title: New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens

Volume: 3 Issue: 2

Author(s): Laurence Bonnafoux, Nathalie Nicod, Frederic Leroux, Berengere Quissac and Francoise Colobert

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Keywords: isoquinoline, halogen, polar organometallic methods, disproportionation, Complexation, chromatographic comparison

Abstract: Regioselective halogen/lithium permutation reactions were carried out on polybrominated biaryls. Thus, highly functionalized, dissymetrically substituted biaryls become easily accessible on gram scale.

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Bonnafoux Laurence, Nicod Nathalie, Leroux Frederic, Quissac Berengere and Colobert Francoise, New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens, Letters in Organic Chemistry 2006; 3 (2) . https://dx.doi.org/10.2174/157017806775224279